NIGK21006U Aqueous Geochemistry

Volume 2025/2026
Education

MSc Programme in Geology-Geoscience

Content

The course attendants will:

  • Learn basics of aqueous speciation, mineral-, gas-, and redox-equilibria, and adsorption-desorption processes.
  • Evaluate water-rock interactions controlling inorganic aqueous geochemistry and element cycling with water movement in the hydrosphere.
  • Combine the use of classical methods and of 1D-reactive transport modeling (PHREEQC), to conduct qualitative and quantitative interpretations of water chemistry development along flow paths (e.g., in aquifers) and diffusion-controlled gradients (e.g., seabed).
  • Trace water chemistry as it develops in the terrestrial hydrological cycle: in rain water, through aquifers and to its discharge, by using major ion chemistry as natural tracers.
  • Work with threats to drinking water quality and to natural environments from contamination.  
  • Formulate and apply problem-specific chemical reactions for aqueous geochemical processes, such as mineral dissolution and precipitation, ion exchange, diffusion and dispersion, surface adsorption and redox processes.

 

Exercises and assignments comprise real datasets, presenting the students with major global issues of today that can be observed, evaluated or solved within the discipline of aqueous geochemistry. Modern examples include: silicate weathering and the carbon cycle; permafrost and wetland hydrochemistry; assessing nitrogen cycling using 2D reactive transport modelling; and ocean acidification.

Learning Outcome

Knowledge: Attendants will acquire knowledge on:

  • Major chemistry of water, water quality, and analysis accuracy. 
  • The relation between aqueous inorganic geochemistry, sediment mineralogy, and water movement/hydrogeology that control geochemical processes/water-rock interaction (mineral/gas dissolution and precipitation/degassing, saturation state and partial gas pressures, ion exchange, surface complexation, redox reactions). 
  • Diffusion and dispersion in relation to aqueous inorganic geochemistry. 
  • Chemical speciation in water, batch and 1D reactive transport modeling with PHREEQC (a free, generic aqueous geochemistry code).

 

Skills: Attendants will acquire skills to:

  • Assess quality of water and water analyses; write and make use of geochemical reaction equations for various water-rock interactions, and equations for diffusion/dispersion;
  • Assess controlling geochemical processes based on water analyses, sediment mineralogy, and hydrogeology;
  • Conduct chemical speciation, batch and 1D reactive transport modeling with PHREEQC.
  • Calculate contaminant retardation and derive contaminant travel times and spreading.

 

Competences: Competences acquired:

  • Break-down data sets of water analyses, sediment mineralogy and hydrology to evaluate qualitatively and quantitatively the geochemical and physical/hydrogeological processes controlling element fluxes and aqueous geochemistry of the hydrosphere, including groundwater chemistry and drinking water quality.
  • Combine and reformulate general geochemical reaction equations for aqueous and solid-aqueous processes into problem-specific reaction equations which clearly express the nature of the problem at hand.
  • To formulate and test hypotheses, and make predictions, regarding groundwater geochemistry by conducting numerical speciation, batch and reactive transport (flow or diffusion) modeling.

Please see Absalon course page.

 

BSc in Geology, Physical Geography, Geosciences, Marine Sciences, Environmental Engineering, Inorganic Chemistry, or equivalent is recommended.
The form of teaching is as flipped classroom which includes a high degree of preparation by the students, introductory lectures by teacher, class exercises and discussions, and group work. During the course each student in addition will work on the own course notes which in the end will form their own "Guide to Aqueous and Environmental Geochemistry".
  • Category
  • Hours
  • Preparation
  • 171
  • Theory exercises
  • 35
  • Total
  • 206
Oral
Individual
Collective
Continuous feedback during the course of the semester
Peer feedback (Students give each other feedback)

During the course, the attendants will receive constructive oral feedback from the teacher and written feedback from peer students to their course notes.

Credit
7,5 ECTS
Type of assessment
On-site written exam, 4 hours under invigilation
Type of assessment details
-
Aid
Only certain aids allowed (see description below)

The course textbook and a calculator are allowed as aids at the exam.

Marking scale
7-point grading scale
Censorship form
No external censorship
Several internal examiners.
Re-exam

Identical to ordinary exam.

Criteria for exam assesment

See Learning Outcome.